Bismuth modified carbon-based electrodes for the determination of selected neonicotinoid insecticides.
نویسندگان
چکیده
Two types of bismuth modified electrodes, a bismuth-film modified glassy carbon (BiF-GCE) and a bismuth bulk modified carbon paste, were applied for the determination of selected nitroguanidine neonicotinoid insecticides. The method based on an ex situ prepared BiF-GCE operated in the differential pulse voltammetric (DPV) mode was applied to determine clothianidin in the concentration range from 2.5 to 23 μg cm⁻³ with a relative standard deviation (RSD) not exceeding 1.5%. The tricresyl phosphate-based carbon paste electrodes (TCP-CPEs), bulk modified with 5 and 20 w/w% of bismuth, showed a different analytical performance in the determination of imidacloprid, regarding the peak shape, potential window, and noise level. The TCP-CPE with 5% Bi was advantageous, and the developed DPV method based on it allowed the determination in the concentration range from 1.7 to 60 μg cm⁻³ with an RSD of 2.4%. To get a deeper insight into the morphology of the bismuth-based sensor surfaces, scanning electron microscopic measurements were performed of both the surface film and the bulk modified electrodes.
منابع مشابه
Electrochemical Determination of Neonicotinoid Insecticide Clothianidin by Nanomaterial based Disposable Electrode
Disposable, selective and low-cost carbon nanotube modified electrodes were fabricated for the electrochemical detection of neonicotinoid insecticide, Clothianidin (CLT). Almost 2 folds’ increase at Clothianidin reduction signal was obtained by using single-walled carbon nanotube modified electrodes (SWCNT-PGE) compared to unmodified electrodes. These nanomaterials modified electrodes developed...
متن کاملDevelopment of novel potentiometric sensors for determination of lidocaine hydrochloride in pharmaceutical preparations, serum and urine samples
This article is focused on the determination of lidocaine hydrochloride as a local anaesthetic drug. A potentiometric method based on modified screen-printed and modified carbon paste ion-selective electrodes was described for the determination of lidocaine hydrochloride in different pharmaceutical preparations. It was based on potentiometric titration of lidocaine hydrochloride using modified ...
متن کاملElectroanalysis of Insecticides at Carbon Paste Electrodes with Particular Emphasis on Selected Neonicotinoid Derivatives
متن کامل
Development of novel potentiometric sensors for determination of lidocaine hydrochloride in pharmaceutical preparations, serum and urine samples
This article is focused on the determination of lidocaine hydrochloride as a local anaesthetic drug. A potentiometric method based on modified screen-printed and modified carbon paste ion-selective electrodes was described for the determination of lidocaine hydrochloride in different pharmaceutical preparations. It was based on potentiometric titration of lidocaine hydrochloride using modified ...
متن کاملStudy and optimization of the necessary conditions for the sensitive determination of the lead ion by a modified carbon paste electrode in environmental water samples
Rapid and facile preparation of the cheap modified electrode materials is an important parameter in development of the efficient electrochemical sensor for industrial scale production and mass-market usage. In the present work, the carbon paste electrode modified with multi-walled carbon nanotubes (MWCNTs) was prepared for sensitive determination of lead (Pb) ion in the presence of bismuth (Bi)...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید
ثبت ناماگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید
ورودعنوان ژورنال:
- Molecules
دوره 16 6 شماره
صفحات -
تاریخ انتشار 2011